Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

西太平洋俯冲板块对中国东北构造演化的影响及其动力学意义   总被引：4，自引：0，他引：4       下载免费PDF全文

田有  马锦程  刘财  冯晅  刘婷婷  朱洪翔  闫冬  李红昊 《地球物理学报》2019,62(3):1071-1082

中国东北地区在古生代期间以众多微陆块的拼合以及古亚洲洋的闭合为特征,其后又经历了中-新生代太平洋构造域及中生代蒙古—鄂霍茨克构造域的叠加与改造,以致东北地区的构造行迹显得极为复杂,而大兴安岭重力梯级带及其西部地区构造演化是否与西太平洋俯冲有关仍然存在争议.本研究利用分布于中国东北、华北地区以及韩国、日本等部分台网所接收的近震与远震走时数据获得了中国东北地区壳幔精细的三维P波速度结构.成像结果显示,太平洋板块持续西向俯冲,俯冲板片的前缘停滞在大兴安岭—太行山重力梯度带以东区域的地幔转换带之中;长白山火山区上地幔存在着显著的低速异常体,推测西太平洋板块的深俯冲脱水导致了上地幔底部岩石的熔点降低,从而形成了大范围的部分熔融物质上涌.通过分析上地幔的速度结构,我们认为由于太平洋板块的大规模西向深俯冲,在大地幔楔中发生板片脱水、低速热物质上涌等复杂的地球动力学过程;俯冲板片前缘带动上地幔中不均匀分布的地幔流强烈作用于上部的岩石圈,这对东北地区深部壳幔结构乃至大兴安岭重力梯级带的形成、演化有着重要的影响.  相似文献   

Variation in the vertical zonality of erodibility and critical shear stress of rill erosion in China's Hengduan Mountains     

Zhengan Su  Donghong Xiong  Jianhui Zhang  Tao Zhou  Hongkun Yang  Yifan Dong  Haidong Fang  Liangtao Shi 《地球表面变化过程与地形》2019,44(1):88-97

Soil erodibility is an essential parameter used in soil erosion prediction. This study selected the Liangshan town watershed to quantify variation in the vertical zonality of rill erodibility (k_r) in China's ecologically fragile Hengduan Mountains. Soil types comprised of yellow–brown (soil A), purple (soil B), and dry-red (soil C) in a descending order of occurrence from the summit to the valley, which roughly corresponds to the vertical climate zone (i.e. cool-high mountain, warm-low mountain, and dry-hot valley sections) of the study area. With elevation, vertical soil zonality varied in both soil organic matter (SOM) content and soil particle-size fractions. A series of rill erosion-based scour experiments were conducted, using water discharge rates of 100, 200, 300, 400, 500, and 600 mL min^-1. Additionally, detachment rates (Dr) were measured under three hydrological conditions (the drainage, saturation, and seepage treatments). Results show that both Dr and flow shear stress (Ʈ) values increased as discharge increased. As elevation increased, the k_r values decreased, while the vertical zonality of critical shear stress (Ʈ_c) values showed no obvious variation. The highest k_r values were observed during the seepage treatment, followed by the saturation treatment then drainage treatment, indicating that variation in vertical hydraulic gradients could significantly alter k_r values. This study also found that land-use types could also alter k_r and Ʈ_c values. Further research, however, is necessary to better quantify the effects of subsurface hydrological conditions and land-use types on k_r under different soil zonalities in China's Hengduan Mountains. © 2018 John Wiley & Sons, Ltd.  相似文献   

Mapping Geochemical Anomalies Through Integrating Random Forest and Metric Learning Methods     

Wang  Ziye  Zuo  Renguang  Dong  Yanni 《Natural Resources Research》2019,28(4):1285-1298

Extracting geochemical anomalies from geochemical exploration data is one of the most important activities in mineral exploration. Geochemical anomaly detection can be regarded as a binary classification problem. The similarity between geochemical samples can be measured by their distance. The key issue of this classification is to find the intrinsic relationship and distance between geochemical samples to separate geochemical anomalies from background. In this paper, a hybrid method that integrates random forest and metric learning (RFML) is used to identify geochemical anomalies related to Fe-polymetallic mineralization in Southwest Fujian Province of China. RFML does not require any specific statistical assumption on geochemical data, nor does it depend on sufficient known mineral occurrences as the prior knowledge. The geochemical anomaly map obtained by the RFML method showed that the known Fe deposits and the generated geochemical anomaly area have strong spatial association. Meanwhile, the receiver operating characteristic curves for the results of RFML and another method, namely maximum margin metric learning, indicated that the RFML method exhibited better performance, suggesting that RFML can be effectively applied to recognize geochemical anomalies.

  相似文献   

西昆仑穆呼锰矿床地质特征、控矿因素及成矿模式     

董志国  张连昌  董飞羽  张帮禄  谢月桥  查斌  彭自栋  王长乐 《吉林大学学报(地球科学版)》2020,50(5):1358-1372

穆呼锰矿床位于西昆仑造山带玛尔坎苏锰矿带东段，研究程度相对薄弱。穆呼锰矿床的含矿地层为上石炭统喀拉阿特河组，自下而上可分为角砾灰岩、钙质杂砂岩和含炭质泥灰岩3个岩性段，具有完整的海侵层序特征，反映了由逐步断陷到稳定沉积的盆地演化过程。锰矿层赋存于第三岩性段炭质泥灰岩中，矿石矿物主要为化学组分纯净的泥晶菱锰矿。根据详细的矿相学观察并综合前人研究成果，笔者认为菱锰矿是初始沉淀的锰（氢）氧化物与有机质通过成岩反应形成的。这种成矿机制需要3个基本条件：丰富的锰质来源、氧化还原分层的海水和有机质的大量埋藏。在穆呼一带，有利于满足以上条件的主要控矿因素包括：伸展拉张的构造背景、强烈的海底热液活动、海侵事件和温暖潮湿的古气候。笔者根据w（Ba）-w（P₂O₅）图解并结合区域对比分析，初步认为穆呼锰矿床的成矿模式可能属于最小含氧量带扩张型。  相似文献   

Numerical investigation on special modes with narrow amplification diagram in harbor oscillations     

Ma  Xiouzhou  Zheng  Zhenjun  Zhang  Xiang  Dong  Guohai 《Ocean Dynamics》2020,70(1):1-19

Ocean Dynamics - In the studies of harbor oscillations, some modes with extremely narrow amplification diagram are significantly common. An extended mild-slope equation and a fully nonlinear...  相似文献   

Dynamic responses of unsaturated half‐space soil to a moving harmonic rectangular load          下载免费PDF全文

Zheng Lu  Ran Fang  Hailin Yao  Cheng Dong  Shaohua Xian 《国际地质力学数值与分析法杂志》2018,42(9):1057-1077

The problem of the dynamic responses of a semi‐infinite unsaturated poroelastic medium subjected to a moving rectangular load is investigated analytical/numerically. The dynamic governing equations are obtained with consideration of the compressibility of solid grain and pore fluid, inertial coupling, and viscous drag as well as capillary pressure in the unsaturated soil, and they can be easily degraded to the complete Biot's theory. Using the Fourier transform, the general solution for the equations is derived in the transformed domain, and then a corresponding boundary value problem is formulated. By introducing fast Fourier transform algorithm, the unsaturated soil vertical displacements, effective stresses, and pore pressures induced by moving load are computed, and some of the calculated results are compared with those for the degenerated solution of saturated soils and confirmed. The influences of the saturation, the load speed, and excitation frequency on the response of the unsaturated half‐space soil are investigated. The numerical results reveal that the effects of these parameters on the dynamic response of the unsaturated soil are significant.  相似文献   

张力腿平台筋腱支撑浮筒结构设计研究     

王火平  金文学  吕东  范志峰  王立权 《海洋工程》2018,36(3):69-75

在张力腿平台筋腱与海底桩基连接后,需要筋腱支撑浮筒为筋腱提供足够的浮力,保证筋腱在平台运抵工作海域之前不会发生倾覆。针对南海油田自主研发的张力腿平台筋腱实际尺寸及设计要求,设计了适用于1 061 mm(40英寸)筋腱、500米水深的张力腿平台筋腱支撑浮筒,并对筋腱支撑浮筒主要受力进行了分析计算,根据所计算的载荷情况对关键部件进行了有限元仿真分析,验证了结构强度的可靠性,并得到了结构的应力集中点与最大变形点,为筋腱支撑浮筒的结构设计提供了参考。  相似文献   

捷联式航空重力扰动矢量解算及误差补偿     

郭栋  孙中苗  吴富梅  张琪 《大地测量与地球动力学》2018,38(12):1295-1301

介绍捷联式航空重力矢量测量的基本原理，利用波数相关滤波（WCF）、比力线性校正的方法对重力扰动的水平和垂向分量进行误差补偿，评定内符合精度。对国产捷联式航空重力矢量仪的某次试验数据进行处理，以验证和评估航空重力矢量仪的性能。结果表明，在半波长分辨率为7.5 km时，6条重复测线的重力扰动水平分量经波数相关滤波处理后，东、北向分量的平均内符合精度分别从9.77 mGal、9.18 mGal提高到5.95 mGal、3.83 mGal；对比力的垂向分量线性校正后，将解算的重力扰动垂向分量再用WCF方法处理，其平均内符合精度从1.27 mGal提高到0.59 mGal。  相似文献   

Degradation of Atenolol with Electrochemical Oxidation at Mixed Metal Oxide Electrodes Assisted by UV Photolysis          下载免费PDF全文

Shumin Zhu  Bingzhi Dong  Shiqing Zhou 《洁净——土壤、空气、水》2018,46(4)

  相似文献